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Electrochemical degradation of three phthalate esters in synthetic wastewater by using a Ce-doped Ti/PbO2 electrode

文献类型： 外文期刊

作者： Deng, Dongli 1 ; Wu, Xiaohua 1 ; Li, Mingyuan 1 ; Qian, Sheng 1 ; Tang, Bobin 3 ; Wei, Shiqiang 1 ; Zhang, Jinzhong 1 ;

作者机构： 1.Southwest Univ, Coll Resources & Environm, Chongqing Key Lab Agr Resources & Environm, Chongqing 400715, Peoples R China

2.Chongqing Ind Polytech Coll, Fac Chem & Pharmaceut Engn, Chongqing 401120, Peoples R China

3.Chongqing Engn Technol Res Ctr Import & Export Fo, Tech Ctr, Chongqing Customs, Chongqing 400020, Peoples R China

关键词： Phthalate esters; Ce-doped Ti/PbO2 electrode; Electrochemical degradation; Energy consumption; Degradation pathways

期刊名称：CHEMOSPHERE （ 影响因子：7.086； 五年影响因子：6.956 ）

ISSN： 0045-6535

年卷期： 2020 年 259 卷

页码：

收录情况： SCI

摘要： A Ce-doped Ti/PbO2 electrode was prepared in a deposition solution containing Ce3+ and Pb2+ ions by electrodeposition, and the surface morphology, crystal structure and elemental states were characterized by SEM, XRD and XPS. The electrode was used to investigate the simultaneous degradation of three phthalate esters (PAEs), i.e., dimethyl phthalate (DMP), diethyl phthalate (DEP) and dibutyl phthalate (DBP) in synthetic wastewaters. The results showed that the electrode exhibited excellent electrocatalytic activity and good reusability and stability, and the removal efficiencies of 5 mg L-1 DBP, DMP and DEP in 0.05 M Na2SO4 (pH 7) reached 98.2%, 95.8% and 81.1% at current density of 25 mA cm(-2) after 10 h degradation, respectively. The degradation processes followed pseudo first-order kinetic model very well, and the observed rate constants of DBP, DEP and DMP were 0.42, 0.40 and 0.29 h(-1), respectively. The energy consumption in three PAEs degradation was also assessed. The main degradation products of the three PAEs were identified by using liquid chromatography-tandem mass spectrometry, and the possible degradation pathways mainly included dealkylation, hydroxyl addition, decarboxylation and benzene ring cleavage. This work is a promising candidate for efficient treatment of multiple PAEs in wastewater and protection of the aquatic ecological environment. (C) 2020 Elsevier Ltd. All rights reserved.

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