文献类型： 外文期刊

作者： Huang, Ruting ¹ ; Zhang, Yeyin ¹ ; Li, Wenqiang ¹ ; Zhang, Wanxia ¹ ; Fang, Yong ¹ ; Zhang, Wenrui ¹ ; Cui, Anqi ¹ ; Ying, Yu ² ; Shi, Xianyang ¹ ;

作者机构： 1.Anhui Univ, Sch Resource & Environm Engn, Informat Mat & Intelligent Sensing Lab Anhui Prov, Anhui Prov Key Lab Wetland Ecosyst Protect & Resto, Hefei 230601, Peoples R China

2.Inst Soil & Fertilizer, Anhui Acad Agr Sci, Key Lab Nutrient Cycling Resources & Environm Anhu, Hefei 230001, Peoples R China

关键词： NiFe-MOF; CO2 reduction; Defect structure; Photocatalytic

期刊名称：JOURNAL OF MATERIALS SCIENCE & TECHNOLOGY （ 影响因子：10.9； 五年影响因子：9.9 ）

ISSN： 1005-0302

年卷期： 2024 年 170 卷

页码：

收录情况： SCI

摘要： In this study, a Ni-Fe metal-organic framework modified by -NH2 and -SH was synthesized using a simple hydrothermal process for enhancing photocatalytic CO2 reduction. As expected, the N2S-NiFe (NH2-BDC/H4DSBDC, 2:1) displayed excellent photocatalytic CO2 reduction activity and high CO selectivity (12,412.23 mu mol g(-1) h(-1) ) under visible light irradiation (lambda >= 420 nm), which is 5 times that of NiFe-MOF. Notably, the excellent photocatalytic performance of N2S-NiFe can benefit from the rich defect trap site caused by the introduction of amino and sulfhydryl groups, accelerating charge transfer and promoting space charge separation, as supported by the photo-electrochemical properties. To better understand the CO2 adsorption mechanism, density functional theory calculations were performed, which revealed that the Niov site has more negative adsorption energy compared with the Feov site. This study provides a simple strategy to establish efficient photocatalysts for CO2 reduction through the modification of organic ligands. (c) 2023 Published by Elsevier Ltd on behalf of The editorial office of Journal of Materials Science & Technology.